MODIFIED TEA LEAVES RESIDUAL FOR NICOTINE ADSORPTION
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Abstract
The boiled tea leaves residual was modified with oleum of weight 1:1 to prepare an adsorbent that is capable to adsorb nicotine on its surface. The surface properties of the sample were studied by using the FT-IR spectroscopy after each treatment resulting obvious peaks that indicate the modification of the sample with oleum and the adsorption of nicotine on its surface. The concentration of nicotine in the prepared solutions was measured by the use of spectral analysis. The change of nicotine΄s adsorption was studied with the change of time. An increase in the adsorbed amount was noticed until the equilibrium was reached after 24hours. In addition, an increase of the adsorbed amount of nicotine with the increase of its initial concentration was observed at the room temperature. The experimental data corresponded with adsorption models of Langmuir, Freundlish and Temkin, besides, a mechanism of the adsorption of nicotine was suggested to occur with the participation of the two nitrogen atoms.
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References
Adnan, M., Ahmad, A., Ahmed, A., Khalid, N., Hayat, I., Ahmed, I., (2013). Chemical composition and sensory evaluation of tea (camellia sinensis) commercialized in Pakistan, Pak. J. Bot., 45(3): 901-907.
AlBezreh, W.Y., Shaheen, A., (1999). A study on the adsorption properties of adsorbents for nicotine prepared starting from Syrian Raw materials. A master degree dissertation, Damascus university, Syria, 24-25.
AlBizreh, W.Y., Almostafa, R., AlJoubbeh, M., (2017). Adsorption of nicotine on Sulfonated compressed coffee waste and study of its surface properties. Journal of Scie
nces, Damascus University, Syria.
Almostafa, R., AlBizreh, W.Y., AlJoubbeh, M., (2017). Sulfonated Carbon of date seeds for nicotine adsorption and ion exchange. Journal of Sciences, Damascus University, Syria.
Altundogan, S.H., Arslan, E.N., Tumen, F., (2007). Copper Removal From Aqueous Solutions By Sugar Beet Pulp Treated By NaOH And Citric Acid. Journal Of Hazardous Materials, 149, 432-439.
Basher, Z., Gupta, A.K., Chattre, A., (2013). Adsorption Capacity of Nicotine From Tobacco Products By Different Adsorbents. International Journal of Computational Engineering Research, Vol 03, Issue, 11.
Basher, Z., Gupta, A.K., Chattre, A., (2014). Adsorption Isotherm Of Separation Of Nicotine In Tobacco Products By Low Cost Adsorbents. IOSR Journal of Applied Physics (IOSR-JAP), Vol. 3, 39-45.
Belitz, H.D., Grosch, W., Schieberle., (2009). Food chemistry, 4th revised extended edition, Springer-Verlag Berlin Heidelberg, 953.
Dada, A.O., Olalekan, A.P., Olatunya, A.M., Dada, O., (2012). Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR Journal of applied chemistry, 3, 38-45.
Elhadi, H.N., Chattree, A., (2016). Alkaloid removal from popular Indian brands of cigarettes using low cost adsorbents. International Journal of Advanced Research, 4 (11), 565-571.
Ghiaci, E.M., Abbaspur, A., Kia, R., Seyedeyn-Azad, F., (2004). Equilibrium isotherm studies for the sorption of benzene, toluene, and phenol onto organo-zeolites and as-synthesized. MCM-41. Sep. Purif. Technol. 40, 217–229.
Grozdanic, N., Calado, M., Kijevcanin, M., Šerbanovic, S., Visak, Z., (2014). Aqueous Nicotine Solutions: pH Measurements And Salting-out Effects-analysis Of The Effective Gibbs Energies Of Hydration And Ionic Strengths Of The Solutions. Serb, Chem Soc, 79 (7), 829–842.
http//www.bob-r.com/ENI/nicotine titration notes-HCl.
Ho, Y.S., Me, K.G., (2000). The kinetics of sorption of divalent metal ions onto sphagnum moss peat. water Res, 34 (3), 735-742.
Kzitcina, A., Koupletskayan, B., (1979). Application of UV, IR, NMR and Mass Spectrometry in Organic Chemistry. Moscow University, 169-231.
Lagergren, S., (1998). About the theory of So-called adsorption of soluble substances. Kung Vetensk, Acad, Hand, 24, 1-39.
Maduro, R.M., Aznar, M., (2007). Liquid-liquid equilibrium of ternary systems containing nicotine. Issue 1, SPEC. ISS. Fluid Phase Equilib. 259, 83–88.
Novotny, T. E., Zhao, F., (1999). Consumption And Production Waste: Another Externality Of Tobacco Use. Tob. Control 8, 75–80.
Osipov, O.A., Minkinv, E., (1965). Hand book of dipole moment. Vishayashcola, Moscow, 164.
Rakic, V., Damjanovic, L., Rac, V., Stosic, D., Dondur, V., Auroux, A., (2010). The adsorption Of Nicotine From Aqueous Solutions On Different Zeolite Structures. water research 44, 2047 – 2057.
Utomo, H.D., (2007). The adsorption of heavy metals by waste tea and coffee residues (Thesis, Doctor of Philosophy). University of Otago. http://hdl.handle.net/10523/159. Adsorption of heavy metal by waste / Http.
Weber, GR.W., Morris, J.C., (1963). Kinetics of adsorption on carbon from solutions. J.Saint Eng. Div, Am. Soc, civil Eng, 89(2), 31-59.